Re: Can you sign up with Adyen directly?
They are the backend payment processor but this is eBay's show so I'm pretty sure you would have to apply directly with eBay.
The difference between Adyen and Paypal, IMO, is that Adyen is designed to be seamlessly integrated with any e-commerce website without the Adyen brand being promoted. Paypal on the other hand is designed to be much more up front, dealing directly with customers, with their branding everywhere they're accepted.
An application directly with Adyen would probably be an application to integrate their payment platform into your website or app, not to sell on eBay.
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