If the card has never been used before, yes it may be used. If it is associated with either a suspended ebay account or limited paypal account, it can not be used.
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Its for a friends UK account which i sell on, he used his mums visa card on paypal in 2007 and it was fine however ebay has now asked us to put a credit card on file or we cannot sell, so i was wondering if we can use the same one as paypal or just use an entropay one.