I am pretty sure VCC's work in Bolivia, but you may want to wait for others to reply. I went to the legal section on Bolivia's paypal, and found this:
This policy applies to users in the following countries: Albania, Algeria, Antigua and Barbuda, Barbados, Belize, Bosnia and Herzegovina, Dominica, Egypt, Fiji, French Polynesia, Grenada, Lesotho, Malawi, New Caledonia, Palau, Saint Kitts and Nevis, Saint Lucia, Seychelles, Trinidad and Tobago, Turks and Caicos.
If you do not want to wait for the automatic transfer, you may manually transfer the amounts in your available PayPal balance to your US bank account or Visa credit card.
Manual transfers to your Visa credit card will incur a $5.00 USD (or equivalent) fee.
Manual transfers to your US bank account are free.
The weird thing though is that Bolivia isn't mentioned in the list of countries, but this is from Paypal Bolivia. Strange...
Vcc works for my country 
